Biodegradable PU Coatings for Textiles and Leather
Degradable coatings are desirable in order to increase the biodegradability of coated materials and simplify waste treatment by removing coatings from textiles. De-coated textiles can be recycled according to the type of fabric without impurities from coating polymers.
Challenges for the textile coating industry
When working with PU, companies are facing multiple challenges: they must comply with the REACH regulation and VOC directive, respect exposure limits in the workplace, answer to the requirements set by voluntary labels such as OEKO-TEX® and the ones needed to obtain an environmental licence.
As consumers - being aware of the effects of plastic waste and microplastics on the environment - are increasingly demanding sustainable and green products, companies need to switch to biodegradable materials to answer to the market demand.
Due to the low susceptibility of PU to physical, chemical and biological factors, and the toxicity of some combustion products, landfilling is still the most common way to process PU waste.
Moreover, some changes in the legislation have a major impact.
For example, the revised European Directive 1999/31/EC about landfilling stipulated that after 1 January 2015, only 25% of municipal waste in comparison to the previous year can be deposited in landfills. From 1 January 2030 onward, this will be further limited to 5%.
The development of biodegradable PU will help companies to make the transition to an eco-friendly and sustainable industry giving them a competitive advantage to producers from outside Europe.
Solutions
GUINEA aims to:
- degrade commercial waterborne PU dispersions (PUD) used for textile and leather coating
- develop degradable PUD
- examine the use of enzymes to degrade PU
These coatings will increase the biodegradability of coated leathers, and thus simplify waste treatment and minimize the environmental impact.
Biodegradable textile coatings will minimize pollution during the user phase (avoiding the formation of persistent microplastics by abrasion) and increase the recyclability of coated polyester or polyamide garments, by selectively removing the PU coating through enzymatic degradation.
GUINEA addresses the textile and leather coating industry, the coating related industry such as formulators and the chemical producers. GUINEA focuses on technical textiles and coated leather products.
Project manager
David De Smet
Researcher "Textile Functionalisation & Surface Modification"
dds@centexbel.be
+32 489 871 019
+32 9 241 86 84
Downloads
Design of Biodegradable PU Textile Coating
Polymers, MDPI
David De Smet, Jente Verjans, Myriam Vanneste (Centexbel) & Miriam Bader, Anke Mondschein (FILK Freiberg Institute gGmbH)
Abstract: Polyurethane (PU) coatings are used in diverse applications such as textile coating. Up to today, landfilling is still the most occurring way of processing PU waste. Biodegradation is an alternative route for processing PU waste and decreases the amount of microplastics in the case of landfilling. In this study, a biodegradable PU textile coating was developed. The PU was characterized via Fourier-transformed infrared (FT-IR) thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC).
The PU was thermoplastic and had a melting point of approximately 33°C. The performance of the coating was studied by assessing the water barrier and mechanical properties. The PU coating completely disintegrated, and the biodegradation of PU was assessed in soil and was almost 60%. Furthermore, the plant toxicity was examined by evaluating seedling emergence and growth.
Keywords: polyurethane; coating; biodegradable; textile
Project financing
Cornet Project, co-financed by VLAIO
Project HBC.2021.0892
1 August 2022– 31 July 2024